Shellfish remains are common in coastal and estuarine archaeological sites, but dating these samples require a correction for the “reservoir effect” a process whereby "old carbon" is recycled and incorporated into marine life especially shellfish inflating their actual age in some cases several centuries.
In 1949, American chemist Willard Libby, who worked on the development of the atomic bomb, published the first set of radiocarbon dates.
His radiocarbon dating technique is the most important development in absolute dating in archaeology and remains the main tool for dating the past 50,000 years.
How It Works: Carbon has 3 isotopic forms: Carbon-12, Carbon-13, and Carbon-14.
The numbers refer to the atomic weight, so Carbon-12 has 6 protons and 6 neutrons, Carbon-13 has 6 protons and 7 neutrons, and Carbon-14 has 6 protons and 8 neutrons.
Limitations and calibration: When Libby was first determining radiocarbon dates, he found that before 1000 BC his dates were earlier than calendar dates.